[(Z)-O-Isopropyl N-phenylthiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)
نویسندگان
چکیده
The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.54 (2)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.1702 (16) Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis mediated by C-H⋯O inter-actions.
منابع مشابه
[(Z)-O-Isopropyl N-(4-chlorophenyl)thiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)
The Au atom in the title compound, [Au(C(10)H(11)ClNOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 172.45 (5)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.134 (3) Å].
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The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P angle = 173.44 (5)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.023 (4) Å]. The N-bound isopropyl group is disordered over two orientations in a 0.618 (15):0.382 (15) ratio.
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The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.060 (3) Å]. In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays bein...
متن کامل[(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-κS](tricyclohexylphosphine-κP)gold(I)
In the title compound, [Au(C(10)H(11)N(2)O(3)S)(C(18)H(33)P)], the gold(I) atom is linearly coordinated within a SP donor set. The distortion from linearity [S-Au-P = 177.54 (3)°] can be traced to an intra-molecular Au⋯O contact of 3.009 (3) Å. In the crystal, layers of mol-ecules are stabilized by a combination of C-H⋯O and C-H⋯π inter-actions.
متن کامل[(Z)-N,O-Disopropylthiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)
In the title compound, [Au(C(7)H(14)NOS)(C(18)H(33)P)], the Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.94 (2)°], with the distortion due to a short intra-molecular Au⋯O contact [2.908 (2) Å].
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